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Nickel-Catalyzed Cross-Coupling Reactions. Copper-catalyzed cross-coupling reactions of non-activated primary, secondary or tertiary alkyl chlorides with phenylmagnesium bromide. Naveen Kosar, Khurshid Ayub, Mazhar A. Gilani, Faheem Shah, Tariq Mahmood. If moisture or water is contact with grignard, grignard is destroyed. i-PrI Acceleration of Negishi Cross-Coupling Reactions. and Pazhamalai Anbarasan, Helfried Neumann, Matthias Beller. Copyright © 2015 Elsevier Ltd. All rights reserved. Bis(imidate)palladium(ii) complexes with labile ligands. Nickel-Mediated Inter- and Intramolecular Reductive Cross-Coupling of Unactivated Alkyl Bromides and Aryl Iodides at Room Temperature. Bidentate Hydroxyalkyl NHC Ligands for the Copper-Catalyzed Asymmetric Allylic Substitution of Allyl Phosphates with Grignard Reagents. Jonathan A. Brekan, Dmitri Chernyak, Kolby L. White, Karl A. Scheidt. Brenda A. Frazier, Peter T. Wolczanski and Emil B. Lobkovsky. Susan L. Zultanski and Gregory C. 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Nickel-Catalyzed Diastereoselective Alkyl–Alkyl Kumada Coupling Reactions. Jimmy Coombs, Dalton Perry, Doo-Hyun Kwon, Christine M. Thomas. 3.04 Alkylations of Nonstabilized Carbanions. Alkynyl Grignards are unique among Grignards for their ability to do SN2 chemistry. Anionic Bismuth(III) chloride cluster with diselenide countercations: Application in C-S cross coupling reactions. the Altmetric Attention Score and how the score is calculated. Frustrated Lewis Pairs beyond the Main Group: Synthesis, Reactivity, and Small Molecule Activation with Cationic Zirconocene–Phosphinoaryloxide Complexes. Takuji Hatakeyama, Toru Hashimoto, Kalum K. A. D. S. Kathriarachchi, Takeshi Zenmyo, Hirofumi Seike, Masaharu Nakamura. Nickel-catalyzed dimerization of pyrrolidinoindoline scaffolds: systematic access to chimonanthines, folicanthines and (+)-WIN 64821. Apr 6, 2015 • ericminikel • Cambridge, MA • chem-20. This article is cited by Nickel-catalyzed cross-coupling of primary alkyl halides with phenylethynyl- and trimethylsilyethynyllithium reagents. K.S. sp3-sp3 Coupling reactions in the synthesis of natural products and biologically active molecules. Homocoupling of heteroaryl/aryl/alkyl Grignard reagents: I Stability and Unimolecular Reactivity of Palladate(II) Complexes [L Reductive Cross-Coupling of Conjugated Arylalkenes and Aryl Bromides with Hydrosilanes by Cooperative Palladium/Copper Catalysis. Oleg Vechorkin, Delphine Barmaz, Valérie Proust and Xile Hu. Stephen M. Goldup, David A. Leigh, Roy T. McBurney, Paul R. McGonigal, Andrew Plant. Oxidative Catalytic Coupling Reactions: Selective Formation of CC and CX Bonds Using Radical Processes. An Organometalllic NiIV Complex That Participates in Competing Transmetalation and C(sp2)–O Bond-Forming Reductive Elimination Reactions. Learn about our remote access options, Albert‐Ludwigs‐Universität Freiburg, Institut für Organische Chemie und Biochemie, Freiburg Institute for Advanced Studies (FRIAS), Albertstrasse 21, 79104 Freiburg (Germany) http://www.breit‐group.uni‐ An efficient protocol for the synthesis of thioethers via iron-catalyzed cross-coupling reaction and its mechanistic investigation. Ruthenium-Catalyzed Regioselective Direct Alkylation of Arenes with Unactivated Alkyl Halides through CH Bond Cleavage. Synthesis of Allylic Alcohols via Cu-Catalyzed Hydrocarbonylative Coupling of Alkynes with Alkyl Halides. Copper-Catalyzed 1,5-Addition of Grignard reagents to Enantioenriched Donor-Acceptor Cyclopropanes with Inversion. Construction of Multiple, Contiguous Quaternary Stereocenters in Acyclic Molecules by Lithiation-Borylation. Tom Verhelst, Zuming Liu, Jens Maes, and Bert U. W. Maes . Ultrasonic activation of the arylation reaction of styrene catalyzed by transition metals. 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